A study of adsorption of some bicyclo [2.2.1] heptane derivatives on graphitized thermal carbon black
| Autor: | A. V. Kiselev, E. V. Kalashnikova, K. D. Shcherbakova, R. S. Petrova |
|---|---|
| Rok vydání: | 1986 |
| Předmět: |
chemistry.chemical_classification
Heptane Internal energy Bicyclic molecule Chemistry Surfaces and Interfaces Carbon black chemistry.chemical_compound Colloid and Surface Chemistry Adsorption Hydrocarbon Physical chemistry Organic chemistry Gas chromatography Physical and Theoretical Chemistry Norbornane |
| Zdroj: | Advances in Colloid and Interface Science. 25:217-226 |
| ISSN: | 0001-8686 |
| DOI: | 10.1016/0001-8686(86)80008-2 |
| Popis: | Retention volumes at zero sample size (Henry's constants of adsorption equilibrium), Kovats' indices and the changes in differential molar internal energy and entropy upon adsorption are found for bicyclo[2.2.1] heptane (norbornane), six isomeric dimethylnorbornanes and 7,7′-bisnorbornane by gas adsorption chromatography on packed columns with GTCB. A molecular statistical calculation of the thermodynamic characteristics of adsorption is carried out and the results are compared with experimental data. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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