Detection and Neutralization of Unsymmetrical Dimethylhydrazine on the Surface of Construction Materials
| Autor: | Alexei K. Buryak, K. E. Polunin, I. A. Polunina, A. V. Ul’yanov |
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| Rok vydání: | 2021 |
| Předmět: |
010304 chemical physics
Inorganic chemistry Hydrazine 02 engineering and technology 021001 nanoscience & nanotechnology Mass spectrometry 01 natural sciences Shungite Unsymmetrical dimethylhydrazine Metal chemistry.chemical_compound Adsorption chemistry Reagent Desorption visual_art 0103 physical sciences visual_art.visual_art_medium Physical and Theoretical Chemistry 0210 nano-technology |
| Zdroj: | Russian Journal of Physical Chemistry A. 95:530-537 |
| ISSN: | 1531-863X 0036-0244 |
| Popis: | Abstract The construction materials that contacted with unsymmetrical dimethylhydrazine and the desorption solutions obtained when treating the contaminated surface of metals and alloys with water and reagents were studied by chromatography and mass spectrometry. Neutralization of unsymmetrical dimethylhydrazine was studied using ozone and shungite. Ozonation makes it possible to destroy the toxicant molecules chemically and physically adsorbed on the surface of metal constructions, due to which they can be reused and utilized. Shungite effectively adsorbs and catalytically decomposes not only unsymmetrical dimethylhydrazine and its transformation products, but also oligomer compounds formed during the storage of hydrazine fuel. Ozonation of spent shungite can increase the efficiency of destructive processes and completeness of its regeneration. |
| Databáze: | OpenAIRE |
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