Chiral binaphthyl receptors bearing imidazolium or urea groups for the recognition of anions
Autor: | N. Jiten Singh, Juyoung Yoon, K.M.K. Swamy, Chang-Hee Lee, So Young Chung, Jaeduk Yoo, Soo Kyung Kwon |
---|---|
Rok vydání: | 2009 |
Předmět: | |
Zdroj: | Journal of Inclusion Phenomena and Macrocyclic Chemistry. 66:107-111 |
ISSN: | 1573-1111 0923-0750 |
DOI: | 10.1007/s10847-009-9658-y |
Popis: | Two new binaphthyl derivatives 1 and 2 bearing two imidazolium, or bisurea groups were investigated as fluorescent chemosensors for the chiral anion recognition. Receptors 1 and 2 displayed a better selectivity for (S)-2-phenylbutylate over (R)-2-phenylbutylate. Isothermal titration calorimeter methods, fluorescence as well as theoretical calculations are utilized to explain chiral selectivity. |
Databáze: | OpenAIRE |
Externí odkaz: |