Chiral binaphthyl receptors bearing imidazolium or urea groups for the recognition of anions

Autor: N. Jiten Singh, Juyoung Yoon, K.M.K. Swamy, Chang-Hee Lee, So Young Chung, Jaeduk Yoo, Soo Kyung Kwon
Rok vydání: 2009
Předmět:
Zdroj: Journal of Inclusion Phenomena and Macrocyclic Chemistry. 66:107-111
ISSN: 1573-1111
0923-0750
DOI: 10.1007/s10847-009-9658-y
Popis: Two new binaphthyl derivatives 1 and 2 bearing two imidazolium, or bisurea groups were investigated as fluorescent chemosensors for the chiral anion recognition. Receptors 1 and 2 displayed a better selectivity for (S)-2-phenylbutylate over (R)-2-phenylbutylate. Isothermal titration calorimeter methods, fluorescence as well as theoretical calculations are utilized to explain chiral selectivity.
Databáze: OpenAIRE