Complex Formation of β-Cyclodextrin with Benzoic Acid and Rutin in Water–Ethanol Solvents: Thermal and Thermodynamic Characteristics
Autor: | Pham Thi Lan, Nguyen Thi Ngoan, Le Hai Khoa, T. R. Usacheva, Dzhovidon Kabirov, Vu Xuan Minh |
---|---|
Rok vydání: | 2021 |
Předmět: |
chemistry.chemical_classification
Ethanol Cyclodextrin Base (chemistry) 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Mole fraction 01 natural sciences 0104 chemical sciences Solvent chemistry.chemical_compound Rutin chemistry Thermal Physical and Theoretical Chemistry 0210 nano-technology Nuclear chemistry Benzoic acid |
Zdroj: | Russian Journal of Physical Chemistry A. 95:887-893 |
ISSN: | 1531-863X 0036-0244 |
DOI: | 10.1134/s0036024421050113 |
Popis: | In this study, the complexes of β-cyclodextrin with benzoic acid and rutin were obtained in water-ethanol solvents. The yields of both complexes in binary mixtures is greater than in pure water and reached maximum values at range of 0.05–0.10 mole fraction of ethanol. The impact of water–ethanol solvent on thermodynamics of complexation between β-cyclodextrin and benzoic acid was analyzed on the base of solvation–thermodynamic approach as a model of inclusion complex formation reaction. |
Databáze: | OpenAIRE |
Externí odkaz: |