The continuing story of the diammoniate of diborane

Autor:	Qianyi Zhao, Ewan J. M. Hamilton, Jiaxuan Li, Xuenian Chen
Rok vydání:	2015
Předmět:	Chemistry Dimer Organic Chemistry Ammonia borane Ionic bonding Hydrogen content Biochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound Hydrogen storage Materials Chemistry Organic chemistry Physical and Theoretical Chemistry Diborane
Zdroj:	Journal of Organometallic Chemistry. 798:24-29
ISSN:	0022-328X
DOI:	10.1016/j.jorganchem.2015.05.027
Popis:	The diammoniate of diborane ([H 2 B(NH 3 ) 2 ][BH 4 ], DADB) is an ionic dimer of ammonia borane (H 3 NBH 3 , AB). It has received much less attention in the past few decades than AB, although it has the same high hydrogen content (19.6%). In this review, the important events in the development of DADB are summarized: its serendipitous discovery, formulation, characterization, formation mechanism, preparation, and relationship with AB. Focus is given to its competing formation with AB and potential application as a hydrogen storage medium.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0794a3ec1f69467c2737dbef756f923c https://doi.org/10.1016/j.jorganchem.2015.05.027 Zobrazit plný text záznamu Full Text from ScienceDirect