Evidence for carbon suboxide, C3O2, as an intermediate product in the cool flame oxidation products of diethyl ether
| Autor: | L.H.S. Roblee, J.T. Agnew, K. Wark |
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| Rok vydání: | 1961 |
| Předmět: |
Reaction mechanism
General Chemical Engineering General Physics and Astronomy Energy Engineering and Power Technology General Chemistry Cool flame Photochemistry Spectral line Intermediate product chemistry.chemical_compound Fuel Technology chemistry Emission spectrum Diethyl ether Carbon suboxide Equivalence ratio |
| Zdroj: | Combustion and Flame. 5:65-70 |
| ISSN: | 0010-2180 |
| DOI: | 10.1016/0010-2180(61)90074-8 |
| Popis: | Emission spectra of two-stage cool flames of a mixture of diethyl ether and air with an equivalence ratio of four have been obtained in the spectral region 3·5 to 18·5 microns. Four emission bands corresponding to known vibrational frequencies for carbon suboxide have been obtained in these spectra. Two additional experiments confirming the presence of carbon suboxide in the products are described, and a reaction mechanism is outlined for the formation of carbon suboxide. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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