Synthesis of a Stable Biphenyl-Bis(carbene) and -Bis(silylene) [M{(NCH2But)2C6H3-3,4}]2 (M = C or Si)

Autor:	Barbara Gehrhus, Peter B. Hitchcock, Michael F. Lappert
Rok vydání:	2005
Předmět:	Inorganic Chemistry Biphenyl chemistry.chemical_compound chemistry Stereochemistry Silylene Carbene Medicinal chemistry Derivative (chemistry)
Zdroj:	Zeitschrift für anorganische und allgemeine Chemie. 631:1383-1386
ISSN:	1521-3749 0044-2313
DOI:	10.1002/zaac.200500005
Popis:	Treatment of the biphenyl derivative [S=C{(NCH2But)2C6H3-3,4}]2 or [Cl2Si{(NCH2But)2C6H3-3,4}]2 with C8K afforded the new bis(carbene) 1 or the first bis(silylene) 2, respectively. The X-ray structure of 2 is presented.
Databáze:	OpenAIRE
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