Main group chemistry of 9-hydroxophenalenone: Syntheses and structural characterization of the alkaline earth and zinc complexes

Autor:	Swadhin K. Mandal, Arup Mukherjee, Carola Schulzke, Prinson P. Samuel
Rok vydání:	2014
Předmět:	Alkaline earth metal Inorganic chemistry Solid-state chemistry.chemical_element General Chemistry Zinc Nuclear magnetic resonance spectroscopy chemistry.chemical_compound Crystallography chemistry Group (periodic table) X-ray crystallography Homoleptic Single crystal
Zdroj:	Journal of Chemical Sciences. 126:1581-1588
ISSN:	0973-7103 0974-3626
DOI:	10.1007/s12039-014-0692-y
Popis:	Herein, we report the synthesis and characterization of 9-hydroxophenalenone based alkaline earth and zinc complexes. The reaction of 9-hydroxophenalenone (HO,O-PLY (1)) with one equivalent of KN(SiMe3)2 and MI2 in THF yields heteroleptic complexes [(O,O-PLY)M(THF)n]I [M = Mg (2), Ca (3), Sr (4), Ba (5); n = 1–4], while use of two equivalents of KN(SiMe3)2 in THF (with respect to PLY) produces homoleptic complex (O,O-PLY)2Mg(THF)2 (6). Moreover, reaction between two equivalents of 1 with one equivalent of ZnMe2 in THF produces complex (O,O-PLY)2Zn(THF)2 (7). All these complexes were characterized by NMR spectroscopy and elemental analyses. The solid state structures of complexes 2, 6 and 7 were established by single crystal X-ray diffraction analysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::077cb2e2f3ffbf8baea259a555bb26a0 https://doi.org/10.1007/s12039-014-0692-y Zobrazit plný text záznamu Plný text ve formátu PDF