Combustion generated nanomaterials: online characterization via an ICP-MS based technique. Part II: resolving power for heterogeneous matrices
| Autor: | Debora Foppiano, E. Gubler Müller, Mohamed Tarik, Christian Ludwig |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Materials science
010401 analytical chemistry 010501 environmental sciences Mass spectrometry Combustion 01 natural sciences 0104 chemical sciences Analytical Chemistry Nanomaterials Characterization (materials science) Chemical engineering Particle-size distribution Calibration Particle Inductively coupled plasma mass spectrometry Spectroscopy 0105 earth and related environmental sciences |
| Zdroj: | Journal of Analytical Atomic Spectrometry. 33:1500-1505 |
| ISSN: | 1364-5544 0267-9477 |
| DOI: | 10.1039/c8ja00067k |
| Popis: | Among the available online techniques to characterize combustion generated nanomaterials, the recently developed RDD-SMPS-ICP-MS (rotating disc diluter-scanning mobility particle sizer-inductively coupled plasma-mass spectrometry) setup is here suggested, due to its ability to provide simultaneously size-resolved elemental and quantitative information with a high time resolution. The successful calibration strategy presented in Part I will be applied here. To assess the resolving power of the technique regarding the elemental composition, two different applications with complex heterogeneous matrixes were considered: a mixture of several metal chlorides particles generated by the reaction of metal oxides (PbO, CdO, CuO, ZnO) with CaCl2·2H2O and secondary formed ZnO nano-objects released during the combustion of impregnated wood. The latter, especially, allowed considering the effect of the heterogeneous nature of a realistic process gas sample, where several gas species are emitted. The results of these experiments showed the ability of the SMPS-ICPMS system to distinguish and quantify the single contribution of a specific element in the overall particle size distribution (PSD). |
| Databáze: | OpenAIRE |
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