Performance of a bimetallic Pd–In catalyst in the selective liquid-phase hydrogenation of internal and terminal alkynes
| Autor: | Michael N. Vargaftik, Galina N. Baeva, Olga P. Tkachenko, Igor S. Mashkovsky, Ilya A. Yakushev, P. V. Markov, Aleksandr V. Rassolov, G. O. Bragina, Aleksandr Yu. Stakheev |
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| Rok vydání: | 2016 |
| Předmět: |
010405 organic chemistry
Inorganic chemistry Alloy Liquid phase General Chemistry engineering.material 010402 general chemistry 01 natural sciences Catalyst poisoning 0104 chemical sciences Catalysis chemistry.chemical_compound chemistry Lindlar catalyst engineering Organic chemistry Selectivity Bimetallic strip |
| Zdroj: | Mendeleev Communications. 26:494-496 |
| ISSN: | 0959-9436 |
| DOI: | 10.1016/j.mencom.2016.11.011 |
| Popis: | The 1% Pd–1% In / MgAl2O4 catalyst demonstrated excellent selectivity in the semi-hydrogenation of internal 1-phenylprop-1-yne, which exceeded the selectivity of a commercial Lindlar catalyst and reference monometallic 0.5% Pd/MgAl2O4 catalyst due to Pd–In alloy formation. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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