Synthesis, characterization and catalytic activity of N-heterocyclic carbene ligated Schiff base palladacycles
| Autor: | Ilknur Babahan, Rukiye Fırıncı, M. Emin Günay, Namık Özdemir |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Schiff base
010405 organic chemistry Aryl Infrared spectroscopy Carbon-13 NMR 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Proton NMR Physical and Theoretical Chemistry Phenylboronic acid Carbene |
| Zdroj: | Inorganica Chimica Acta. 522:120360 |
| ISSN: | 0020-1693 |
| DOI: | 10.1016/j.ica.2021.120360 |
| Popis: | A series of N-heterocyclic carbene (NHC) ligated Schiff base palladacycles were synthesized by the reaction of μ-acetato-bridged Schiff base palladacycles (PdL1-2) with imidazolium salts (a-c). The new NHC ligated palladacycles were fully characterized using 1H NMR, 13C NMR, infrared spectroscopy, MS analysis, and single-crystal X-ray diffraction for one complex (PdL1). Further exploration of the catalytic application of the palladacycles for Suzuki-Miyaura cross-coupling reactions of aryl bromides with phenylboronic acid was carried out. It was determined that the new dimeric imine-palladacycle (PdL2) exhibits the highest catalytic activity among the coupling compounds in this study. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect