ChemInform Abstract: Vilsmeier-Haack Reaction on Some 3-Buten-2-ols
| Autor: | M Sreenivasulu, Krishna Gs Rao |
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| Rok vydání: | 1988 |
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| Zdroj: | ChemInform. 19 |
| ISSN: | 0931-7597 |
| Popis: | Vilsmeier-Haack reaction of $R_7R_8C:C(R_9)C(OH)(R_{10})CHR_{11}R_{12} (R_7, R_9, R_{10}, R_{12} = H, Me$; $R_8 = Me, Et, Pr, H$; $R_{11} = H, Me, Et)$ gave 6-26% benzenes I $(R_1 = CHO$; $R_2, R_4, R_6 = H, Me$; $R_3 = Me, CHO$; $R_5 = H, Me, Et, CHO)$. The presence of at least 5 appropriate participating C atoms on the butenol backbone was essential for formylative benzocyclization to occur. |
| Databáze: | OpenAIRE |
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