Kinetic Studies on the Thermal Decomposition of trans-2,3-Dimethyl-1-tri-tert-butylsilyl-1-triisopropylsilylsilirane and the Mechanism of Silylene Generation

Autor:	Dwight A. Trieber, Peter P. Gaspar, Ping Jiang
Rok vydání:	2003
Předmět:	Inorganic Chemistry chemistry.chemical_compound Mechanism (philosophy) Chemistry Magnesium Yield (chemistry) Organic Chemistry Thermal decomposition Silylene chemistry.chemical_element Physical and Theoretical Chemistry Photochemistry Kinetic energy
Zdroj:	Organometallics. 22:2233-2239
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om0206251
Popis:	trans-2,3-Dimethyl-1-tri-tert-butylsilyl-1-triisopropylsilylsilirane (1) has been prepared in 98% yield by the treatment of (tBu3Si)(iPr3Si)SiBr2 with activated magnesium in the presence of trans-2...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::07498a72ee48933676fb89ee27149298 https://doi.org/10.1021/om0206251 Zobrazit plný text záznamu