Thermodynamic favorable CO2 conversion via vicinal diols and propargylic alcohols: A metal-free catalytic method

Autor:	Kan Zhang, Ping Liu, Li-Hua Han, Jingyuan Li, Qing-Wen Song, Qian-Xia Zhang, Xiao-Fang Sun
Rok vydání:	2020
Předmět:	Chemistry Organocatalysis 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 0210 nano-technology 01 natural sciences Combinatorial chemistry Vicinal Catalytic method 0104 chemical sciences
Zdroj:	Chinese Chemical Letters. 31:341-344
ISSN:	1001-8417
DOI:	10.1016/j.cclet.2019.06.030
Popis:	Organocatalysis represents a promising field in chemical fixation of CO2. Herein, a facile metal-free strategy was reported for the one-pot preparation of cyclic carbonates and α-hydroxy ketones from vicinal diols, propargylic alcohols and CO2. Wide scope of vicinal diols and propargylic alcohols was demonstrated to be efficient under the DBU-catalyzed conditions. A plausible mechanism was proposed, which included detailed main and side reactions under the metal-free conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0745eeb41fe30b675111637c70a55e4d https://doi.org/10.1016/j.cclet.2019.06.030 Zobrazit plný text záznamu Full Text from ScienceDirect