ChemInform Abstract: Synthesis of Geminal Bis- and Tristriazoles: Exploration of Unconventional Azide Chemistry
Autor: | Hellmuth Erhardt, Fabian Mohr, Stefan F. Kirsch |
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Rok vydání: | 2016 |
Předmět: | |
Zdroj: | ChemInform. 47 |
ISSN: | 0931-7597 |
Popis: | A range of geminal bis- and tristriazoles are presented. These rare and hardly studied compound classes were easily synthesized using ethyl 2,2-diazido-3-oxobutanoate as the common starting point. Firstly, CuAAC-reaction with an alkyne afforded the corresponding deacetylated bistriazoles. Upon further azidation yielding azidomethylenebistriazoles, a second CuAAC-functionalization then led to the creation of the geminal tristriazole compounds. |
Databáze: | OpenAIRE |
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