Influence of defect type on hydrogen passivation efficacy in multicrystalline silicon solar cells

Autor: Harold Dekkers, Annika Zuschlag, Tonio Buonassisi, Emanuele Cornagliotti, Gabriel Micard, David P. Fenning, Giso Hahn, Gianluca Coletti, Steve Hudelson, Bonna Newman, Barry Lai, Mariana I. Bertoni
Rok vydání: 2010
Předmět:
Zdroj: Progress in Photovoltaics: Research and Applications. 19:187-191
ISSN: 1062-7995
Popis: We examine the effectiveness of hydrogen passivation as a function of defect type and microstructure at grain boundaries (GBs) in multicrystalline silicon. We analyze a solar cell with alternating mm-wide bare and SiNx-coated stripes using laser-beam-induced current, electron backscatter diffraction, X-ray fluorescence microscopy, and defect etching to correlate pre- and post-hydrogenation recombination activity with GB character, density of iron-silicide nanoprecipitates, and dislocations. A strong correlation was found between GB recombination activity and the nature/density of etch pits along the boundaries, while iron silicide precipitates above detection limits were found to play a less significant role. Copyright © 2010 John Wiley & Sons, Ltd.
Databáze: OpenAIRE