Diode laser atomic absorption using a new reference method

Autor: P.E. Walters, J.D. Winefordner, Tye E. Barber, M.W. Wensing
Rok vydání: 1991
Předmět:
Zdroj: Spectrochimica Acta Part B: Atomic Spectroscopy. 46:1009-1014
ISSN: 0584-8547
DOI: 10.1016/0584-8547(91)80097-m
Popis: A diode laser was used as the source for atomic absorption spectroscopy. To overcome the frequency instability and drift of the laser, a new referencing approach is proposed. The frequency of the laser is modulated across the rubidium transition at 780.02 nm, and the absorption signal is detected in an air/hydrogen flame. The absorption signal is processed by a lock-in amplifier. The reference signal for the lock-in amplifier is generated by shaping the absorption signal from a Rb atomic vapor cell into a square wave. As the laser frequency drifts, no phase change occurs between the reference and analytical signals, eliminating noise and signal loss that would have been caused by using a reference method which does not follow the fluctuations of the laser.
Databáze: OpenAIRE