Über Metallalkyl- and Arylverbindungen LIV. Neue Tripheny1methyl-Verbindungen des Kaliums: [KCPh3(PMDTA)], [KCPh3(DIGLYM]n und [KCPh3(THF)]n

Autor:	Erwin Weiss, Heiko Viebrock, Thomas Panther, Ulrich Behrens
Rok vydání:	1995
Předmět:	PMDTA Stereochemistry Organic Chemistry Diglyme Crystal structure Biochemistry Medicinal chemistry Inorganic Chemistry Crystal chemistry.chemical_compound chemistry Materials Chemistry Sheet structure Molecule Lewis acids and bases Physical and Theoretical Chemistry
Zdroj:	Journal of Organometallic Chemistry. 491:19-25
ISSN:	0022-328X
DOI:	10.1016/0022-328x(94)05209-t
Popis:	Solvates of triphenylmethyl potassium have been prepared with three different Lewis bases and their crystal structures determined by X-ray diffraction methods. In [KCPh 3 (PMDTA)] (bd1) (PMDTA  N,N,N′,N″,N″-pentamethyl-diethylenetriamine) discrete molecules are observed whereas the solvates with DIGLYME (MeOCH 2 CH 2 0CH 2 CH 2 OMe) and THF are polymeric in the crystal: [KCPh 3 (DIGLYME)] n ( 32 , zigzag-chain structure) [KCPh 3 (THF)] n (3, sheet structure).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::06cf14d40681e20e4547b399ea9a8343 https://doi.org/10.1016/0022-328x(94)05209-t Zobrazit plný text záznamu Full Text from ScienceDirect