Synthesis of Perfluoroalkylated Carboranes by Cross-Metathesis of Allylcarboranes and Perfluoroalkylpropenes

Autor:	Zbyněk Janoušek, Martin Dračínský, Martin Kotora, Barbara Eignerová
Rok vydání:	2010
Předmět:	Reaction conditions Chemistry Organic Chemistry Carborane Organic chemistry chemistry.chemical_element Moiety Metathesis Combinatorial chemistry Catalysis Ruthenium
Zdroj:	Synlett. 2010:885-888
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0029-1219546
Popis:	A ruthenium complex (Hoveyda-Grubbs second-generation) catalyzed cross-metathesis of allylcarboranes with perfluoroalkylpropenes under standard reaction conditions furnished perfluoroalkylated carboranes in good isolated yields (31-53%). The reaction proceeded with various carboranes and carborane sandwich complexes bearing the bridging allylthioether moiety. This method constitutes a simple and versatile procedure for the preparation of fluorophilic carboranes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::06b9b0abd113bcd2ca25279208cffc42 https://doi.org/10.1055/s-0029-1219546 Zobrazit plný text záznamu