Effect of the alloy on micro-structured reactors for methanol steam reforming
| Autor: | Mario Montes, José Antonio Odriozola, Oihane Sanz, Ion Velasco, F.J. Echave |
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| Rok vydání: | 2013 |
| Předmět: |
inorganic chemicals
Materials science Metallurgy Alloy Oxide chemistry.chemical_element General Chemistry engineering.material complex mixtures Catalysis Brass Steam reforming chemistry.chemical_compound chemistry Chemical engineering Aluminium visual_art visual_art.visual_art_medium engineering Dimethyl ether Methanol |
| Zdroj: | Catalysis Today. 213:145-154 |
| ISSN: | 0920-5861 |
| DOI: | 10.1016/j.cattod.2013.02.027 |
| Popis: | Micro-monoliths and foams made of aluminium, Fecralloy ® and brass were studied as substrates for structured systems for methanol steam reforming (MSR). All the alloys exhibited very adherent oxide layer produced by pre-treatment to improve the adhesion between substrate and catalyst. 2.5% Pd/ZnO catalyst was prepared and deposited on structured substrates. Both, good catalyst adhesion and stable catalytic performance were achieved in the case of brass micro-monoliths. The Fecralloy ® and aluminium substrates reacted with the catalytic active components resulting in catalyst modification. The aluminium based substrates promoted dimethyl ether (DME) formation. Aluminium foam produced better performance than aluminium micro-monoliths that could be related to improved mass and heat transfer properties in foams. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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