Bonding effect of plasma-irradiated PET films can be preserved after soaking in various liquid reagents

Autor:	Yukiko Izumi, Tamio Endo, Yoshinobu Nakamura, Sanapa Lakshmi Reddy, Tetsuo Tsuchiya, Shigehisa Tomita, Hiroaki Nishikawa, Kenichi Uehara, Reji Philip, Kazuya Hanada, Miyoshi Yokura
Rok vydání:	2014
Předmět:	Physics and Astronomy (miscellaneous) Chemistry Reagent Inorganic chemistry General Engineering General Physics and Astronomy Ionic bonding Organic chemistry Irradiation Plasma Condensation reaction Alkali metal Chemical reaction
Zdroj:	Japanese Journal of Applied Physics. 53:05FB21
ISSN:	1347-4065 0021-4922
DOI:	10.7567/jjap.53.05fb21
Popis:	To clarify the bonding mechanism for the plasma-irradiated PET films and the origin of the long lifetime of the bonding ability, we soaked the irradiated films in various types of liquid reagent, then tried to bond them by heat-pressing. The irradiated films do not lose the bonding ability after soaking in water, acid, alkali, and organic solvents, whereas they lose it after soaking in ionic solutions of AlCl3 and FeCl3. The COOH is created on the surface by the irradiation, but it is consumed by the chemical reaction with Al and Fe ions. This is the origin of the inactivation of the irradiated surface and the disappearance of the bonding ability after the soaking. The result supports our proposal of "dehydrated condensation reaction" concerning COOH as the bonding mechanism. The irradiated films should be stable in a normal atmosphere for a long time because they are not subjected to water, acid, alkali, and organic solvents.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::06aa34cb81f7f92702a6811e5554ede3 https://doi.org/10.7567/jjap.53.05fb21 Zobrazit plný text záznamu