Step-growth polymerization of unsaturated aldehydes with diaminodiphenylmethane
| Autor: | Anton Šebenik |
|---|---|
| Rok vydání: | 1998 |
| Předmět: |
chemistry.chemical_classification
Reaction mechanism Double bond technology industry and agriculture Surfaces and Interfaces Aldehyde Surfaces Coatings and Films Step-growth polymerization chemistry.chemical_compound Monomer chemistry Polymerization Chemistry (miscellaneous) Diamine Polymer chemistry Crotonaldehyde |
| Zdroj: | Journal of Coatings Technology. 70:95-100 |
| ISSN: | 0361-8773 |
| DOI: | 10.1007/bf02720502 |
| Popis: | Step-growth polymerization of diaminodiphenylmethane and unsaturated aldehydes (crotonaldehyde, cinnamaldehyde) proceeded easily in toluene at reflux temperature. Resins with molecular weights up to 1,500 g/mol were formed. In the first step of the reaction, the amino and the aldehyde groups reaction were predominate while the double bonds dominated to a lesser extent. The portion of unreacted monomers was under one percent. The resins consisted of oligomers with -CHNH-, -CH=N-, and -CH=CH-groups, which further reacted to form highly crosslinked resins. Kinetic data, the heat of the addition, the heat of condensation, and the activation energy were calculated. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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