Rasta Resin-TBD-Catalyzed γ-Selective Morita–Baylis–Hillman Reactions of α,γ-Disubstituted Allenones

Autor: Patrick H. Toy, Shuang Ma, Yun-Chin Yang
Rok vydání: 2015
Předmět:
Zdroj: Synlett. 26:1732-1736
ISSN: 1437-2096
0936-5214
DOI: 10.1055/s-0034-1380691
Popis: Rasta resin-TBD (RR-TBD) was found to be an efficient organocatalyst for γ-selective Morita–Baylis–Hillman reactions between α,γ-disubstituted allenones and aryl aldehydes. In these reactions the heterogeneous nature of RR-TBD greatly facilitated product isolation since the catalyst could be separated simply by filtration.
Databáze: OpenAIRE