A highly dl-stereoselective pinacolization of aromatic aldehydes mediated by titanium trichloride in dichloromethane

Autor:	Angelo Clerici, Ombretta Porta, Laura Clerici
Rok vydání:	1996
Předmět:	chemistry.chemical_compound chemistry Titanium trichloride Organic Chemistry Drug Discovery Anhydrous Organic chemistry Stereoselectivity Biochemistry Dichloromethane
Zdroj:	Tetrahedron Letters. 37:3035-3038
ISSN:	0040-4039
DOI:	10.1016/0040-4039(96)00462-5
Popis:	Aromatic aldehydes are stereoselectively coupled to dl-hydrobenzoins on treatment with anhydrous TiCl3/CH2Cl2 solution at room temperature. The observed stereochemistry is briefly discussed in term of Ti(IV)-bridging control.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::06376e1ebfe0ca53e41f84ad6d3a3f06 https://doi.org/10.1016/0040-4039(96)00462-5 Zobrazit plný text záznamu Full Text from ScienceDirect