Volumetric properties of dilute (d-glucose + H2O) solutions at temperatures from (293.15 to 433.15) K and pressures from (0.10 to 50.00) MPa
| Autor: | Jeffery C. Seitz, G. W. Rhett, M. D. Schulte, A. S. Hall |
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| Rok vydání: | 2019 |
| Předmět: |
Molar
Aqueous solution Chemistry Analytical chemistry 02 engineering and technology 010402 general chemistry 01 natural sciences Atomic and Molecular Physics and Optics 0104 chemical sciences Dilution chemistry.chemical_compound 020401 chemical engineering D-Glucose General Materials Science 0204 chemical engineering Physical and Theoretical Chemistry |
| Zdroj: | The Journal of Chemical Thermodynamics. 128:372-382 |
| ISSN: | 0021-9614 |
| Popis: | The densities of aqueous solutions of d -glucose were measured at temperatures from (293.15 to 433.15) K and pressures from (0.10 to 50.00) MPa using a vibrating-tube densimeter. Apparent molar volumes Vφ,m and partial molar volumes at infinite dilution V∞ were calculated from the experimental results. V∞ increases as temperature increases and varies linearly with temperature above ∼300 K. In addition, V∞ does not vary as a function of pressure up to 50.0 MPa. Comparison of these results with previous studies indicate excellent agreement and significantly extend the experimental database for aqueous solutions of d -glucose to elevated temperatures and pressures. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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