Manipulating Slow Magnetic Relaxation by Light in a Charge Transfer {Fe 2 Co} Complex

Autor: Osamu Sato, Shinji Kanegawa, Shuqi Wu, Junqiu Li, Sheng-Qun Su
Rok vydání: 2020
Předmět:
Zdroj: Chemistry – A European Journal. 26:3259-3263
ISSN: 1521-3765
0947-6539
Popis: Some cyanide-bridged complexes are known for exhibiting slow magnetic relaxation behavior in a light-induced metastable state. Herein, an unexpected reverse effect is observed for the first time in the S= 1 / 2 {FeII LS -CoIII LS -FeIII LS } (HS=high spin, LS=low spin) ground state of a novel V-shaped trinuclear cyanide-bridged {Fe2 Co} complex. In this complex, light-switchable iron-cobalt charge transfer with repeatable off/on switching of slow magnetic relaxation is discovered upon alternating laser irradiation at 785 and 560 nm. An important characteristic of the present compound is that the S= 1 / 2 ground state exhibits slow magnetic relaxation before irradiation, whereas this is accelerated after irradiation. This is different from the typical behavior, where the light-induced metastable state exhibits slow magnetic relaxation.
Databáze: OpenAIRE
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