Electrochemical and quantum chemical studies of some azomethine compounds as corrosion inhibitors for mild steel in 1M hydrochloric acid
| Autor: | Djamel Daoud, Mousa Al-Noaimi, Saifi Issaadi, Salah Chafaa, Hanane Hamani, Tahar Douadi |
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| Rok vydání: | 2014 |
| Předmět: |
Chemistry
General Chemical Engineering Inorganic chemistry Langmuir adsorption model Hydrochloric acid General Chemistry Electrochemistry Quantum chemistry Dielectric spectroscopy Corrosion symbols.namesake chemistry.chemical_compound Adsorption symbols General Materials Science Polarization (electrochemistry) |
| Zdroj: | Corrosion Science. 88:234-245 |
| ISSN: | 0010-938X |
| DOI: | 10.1016/j.corsci.2014.07.044 |
| Popis: | The corrosion inhibition effect of new azomethine compounds: PhN N C (COCH 3 ) NC 6 H 4 Y {Y = OCH 3 (SB 1 ), CH 3 (SB 2 ), H (SB 3 ), Br (SB 4 ) and Y = Cl (SB 5 )} on mild steel in 1 M HCl, was investigated using potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and quantum chemistry analysis. It has been found that the inhibition efficiency increased with increasing inhibitor concentration. The polarization curves showed that these Schiff bases function as mixed inhibitors. The adsorption of studied compounds on mild steel surface was found to follow the Langmuir isotherm. Molecular modeling was used to correlate corrosion inhibition properties and calculated quantum chemical parameters. |
| Databáze: | OpenAIRE |
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