Selective Synthesis of Fluoro-, Fluorohydro-, and Chlorofluorosilanes from Hydrosilanes with the Use of a CuCl2(CuI)/KF Reagent

Autor:	Atsutaka Kunai, Mitsuo Ishikawa, Tomohiro Sakurai, Eiji Toyoda
Rok vydání:	1996
Předmět:	Inorganic Chemistry Chemistry Reagent Organic Chemistry Physical and Theoretical Chemistry Medicinal chemistry Catalysis
Zdroj:	Organometallics. 15:2478-2482
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om950787f
Popis:	A selective synthesis of fluoro-, fluorohydro-, and chlorofluorosilanes from hydrosilanes has been examined. The reaction of Me2PhSiH and MePh2SiH with a mixture consisting of 2 equiv of CuCl2, 1 equiv of KF, and a catalytic amount of CuI in THF at room temperature afforded Me2PhSiF and MePh2SiF in high yields, respectively. With slight modification of this reaction, n-Hex2SiHF, Ph2SiHF, MeMesSiHF, MePhSiHF, PhSiH2F, and PhSiHF2 could be readily prepared from the corresponding polyhydrosilanes selectively in high yields. Treatment of MePhSiHF and Ph2SiHF with 2 equiv of CuCl2 in the presence of a catalytic amount of CuI afforded the respective chlorofluorosilanes, MePhSiClF and Ph2SiClF.
Databáze:	OpenAIRE
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