A catalyst-free 1,4-Michael-type reaction of in situ generated ortho-quinone methides (o-QMs) with dithiocarbamic acid salts in water

Autor:	Meisam Shabanian, Fezzeh Aryanasab
Rok vydání:	2019
Předmět:	In situ chemistry.chemical_classification chemistry 010405 organic chemistry Organic chemistry General Chemistry 010402 general chemistry Dithiocarbamate 01 natural sciences 0104 chemical sciences Conjugate Catalysis Quinone
Zdroj:	Journal of the Iranian Chemical Society. 16:1703-1713
ISSN:	1735-2428 1735-207X
DOI:	10.1007/s13738-019-01644-z
Popis:	A catalyst-free conjugate addition of dithiocarbamic acid salts to in situ generated ortho-quinone methides (o-QMs) was investigated for the first time. Several dithiocarbamate derivatives of 4-hydroxycoumarine, 4-hydroxypyrone and 2-naphthol were synthesized in moderate-to-good yields in water at room temperature. Catalyst-free addition of dithiocarbamic acid salts to in situ generated o-QMs in water at room temperature.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::05fc35eae5dc58ca40b4906fddaee4e4 https://doi.org/10.1007/s13738-019-01644-z Zobrazit plný text záznamu Full text from SpringerLink