Photochemical Activation of Sulfur Hexafluoride: A Tool for Fluorination and Pentafluorosulfanylation Reactions

Autor: Hans-Achim Wagenknecht, David Rombach
Rok vydání: 2022
Předmět:
Zdroj: Synthesis. 54:4883-4894
ISSN: 1437-210X
0039-7881
Popis: The photoactivation of notoriously inert sulfur hexafluoride represents a challenge for photochemistry. This short review summarizes recently published efforts and the corresponding photochemical mechanisms for switching between the fluorination and pentafluorosulfanylation reactivity of organic substrates.1 Introduction2 Sulfur Hexafluoride (SF6)3 The Pentafluorosulfanyl (SF5) Group4 Photoredox Catalytic Activation of SF6 5 Conclusions
Databáze: OpenAIRE