Transformations of pyridine bases on a nickel-aluminum catalyst

Autor:	V. V. Antonova, V. K. Promonenkov, B. F. Ustavshchikov, T. I. Ovchinnikova, K. P. Bespalov, T. N. Serova
Rok vydání:	1982
Předmět:	Chemistry Organic Chemistry chemistry.chemical_element Carbon-13 NMR Ring (chemistry) Bond order Catalysis chemistry.chemical_compound Nickel Chemical bond Pyridine Polymer chemistry Organic chemistry Thermal stability
Zdroj:	Chemistry of Heterocyclic Compounds. 18:280-283
ISSN:	1573-8353 0009-3122
Popis:	The electronic structures of some pyridine bases are analyzed by means of 1H and 13C NMR spectroscopic data for substituted pyridines and the calculated bond orders in the pyridine ring. The differences in the chemical bonds in the pyridine ring of isomeric methylpyridines and the carbon—carbon bonds between the ring and the methyl groups in these compounds are in agreement with the experimental data on the thermal stability of the simplest pyridine bases and the gas-phase transformation of the isomeric methylpyridines on an industrial nickel—aluminum catalyst. The possibility of obtaining mono- or dialkylpyridines under these conditions, depending on the structure of the starting pyridine bases, is demonstrated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::05d6b0a1dd55c5afda97ebec92652b98 https://doi.org/10.1007/bf00522129 Zobrazit plný text záznamu Full text from SpringerLink