Intramolecular hydrogen transfer from the alkyl substituent of a phosphine ligand to a metal atom upon the irradiation of tungsten phosphine hydride complexes

Autor:	Yu. V. Gak, L. M. Ioffe, Viktor D. Makhaev, A. P. Pivovarov, A. P. Borisov, Yu. G. Borod'ko
Rok vydání:	1987
Předmět:	chemistry.chemical_classification Hydrogen Hydride Chemistry Ligand Substituent chemistry.chemical_element General Chemistry Photochemistry chemistry.chemical_compound Molybdenum Intramolecular force Alkyl Phosphine
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 36:928-930
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00956338
Popis:	1. An intramolecular hydrogen transfer from an alkyl substituent of a phosphine ligand to the metal atom was discovered upon the UV irradiation of WH4(PRPh2)4 complexes, R=CD3 and C2D5. 2. The photochemical activation of methane bonds by molybdenum phosphine hydride complexes is possible in principle.
Databáze:	OpenAIRE
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