Redistribution of alkyl groups in organolead compounds in the presence of methylaluminium dichloride with trimethyllead chloride, dimethyllead dichloride, and lead chloride
| Autor: | K. Jaworski, M. Boleslawski, Stanisław Pasynkiewicz |
|---|---|
| Rok vydání: | 1975 |
| Předmět: |
chemistry.chemical_classification
Reaction mechanism Catalytic complex Lead chloride Organic Chemistry Inorganic chemistry Biochemistry Chloride Inorganic Chemistry chemistry Polymer chemistry Materials Chemistry medicine Redistribution (chemistry) Physical and Theoretical Chemistry Alkyl medicine.drug |
| Zdroj: | Journal of Organometallic Chemistry. 92:175-180 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(00)92087-4 |
| Popis: | The redistribution reaction of alkyl groups between tetramethyl- and tetraethyl-lead catalysed by methylaluminium dichloride complexes with trimethyllead chloride, dimethyllead dichloride, and lead chloride has been studied. On the basis of the results obtained the active catalytic complex has been defined, and a reaction mechanism for the redistribution is proposed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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