Measurement and correlation of the solubility of 4-aminoantipyrine in nine mono and water + ethanol mixed solvents at temperatures from (299.05 to 338.35) K
| Autor: | Jiejie Dong, Fang Wang, Guangyi Zhou, Lei Ding, Baohua Wang |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
UNIQUAC
Extraction (chemistry) Ethyl acetate Thermodynamics 02 engineering and technology 010402 general chemistry Condensed Matter Physics 01 natural sciences Atomic and Molecular Physics and Optics 0104 chemical sciences Electronic Optical and Magnetic Materials law.invention chemistry.chemical_compound 020401 chemical engineering chemistry law Materials Chemistry Non-random two-liquid model Gravimetric analysis 0204 chemical engineering Physical and Theoretical Chemistry Solubility Crystallization Dissolution Spectroscopy |
| Zdroj: | Journal of Molecular Liquids. 244:46-54 |
| ISSN: | 0167-7322 |
| DOI: | 10.1016/j.molliq.2017.08.116 |
| Popis: | In this study, the aim is to obtain new solubility data, correlation equation parameters of 4-aminoantipyrine and thermodynamic parameters in the dissolution process. All this would be useful for optimizing the crystallization and extraction process of 4-aminoantipyrine. The solubility of 4-aminoantipyrine was experimentally measured in mono solvents including methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, acetone, ethyl acetate, water and binary mixtures (water + ethanol) at (299.05 to 338.35) K and atmospheric pressure by using a gravimetric method. The experimental solubility in mono solvents was correlated by the Apelblat equation, van't Hoff equation, λh equation, nonrandom two-liquid (NRTL) equation and universal quasichemical (UNIQUAC) equation. The solubility in the binary mixed solvents was correlated by the Apelblat equation, van't Hoff equation, λh equation, NRTL equation, UNIQUAC equation and Jouyban-Acree-van't Hoff equation. The correlated values based on all the selected equations showed good agreement with the experimental values. |
| Databáze: | OpenAIRE |
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