Cooperative dihydrogen activation at a Na(i)2/Mg(i)2 ensemble

Autor:	Han-Ying Liu, Samuel E. Neale, Michael S. Hill, Mary F. Mahon, Claire L. McMullin, Benjamin L. Morrison
Rok vydání:	2023
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical Communications. 59:3846-3849
ISSN:	1364-548X 1359-7345
DOI:	10.1039/d3cc00710c
Popis:	[{SiNDipp}MgNa]2 ({SiNDipp} = {CH2SiMe2N(Dipp)}2; Dipp = 2,6-i-Pr2C6H3) reacts directly with H2 in a process, which computational studies suggest, is dictated by the frontier MOs of both H2 and the low oxidation state s-block assembly.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::057488f5b90f4269444cb6c1f4f3b1e8 https://doi.org/10.1039/d3cc00710c Zobrazit plný text záznamu