Flexible supercapacitor based on polyaniline nanowires/carbon cloth with both high gravimetric and area-normalized capacitance

Autor: Kuei-Hsien Chen, Yu-Kuei Hsu, Li-Chyong Chen, Ying Ying Horng, Chia Chun Chen, Yi Chen Lu
Rok vydání: 2010
Předmět:
Zdroj: Journal of Power Sources. 195:4418-4422
ISSN: 0378-7753
DOI: 10.1016/j.jpowsour.2010.01.046
Popis: Flexible supercapacitor is successfully fabricated using polyaniline nanowires/carbon cloth (PANI-NWs/CC) nanocomposite. High gravimetric capacitance of 1079 F g−1 at a specific energy of 100.9 Wh kg−1 and a specific power of 12.1 kW kg−1 is obtained. Moreover, this approach also offers an exceptionally high area-normalized capacitance of 1.8 F cm−2. The diffusion length of protons within the PANI-NWs is estimated to be about 60 nm by electrochemical impedance analysis, which indicates that the electrochemical performance of the electrode is not limited by the thickness of PANI-NWs. The electrochemical performance of PANI-NWS/CC remains without any deterioration, even when the cell is bent under high curvature. These results clearly present a cost-effective and simple method of fabrication of the nanostructured polymers with enormous potential in flexible energy storage device applications.
Databáze: OpenAIRE