PALLADIUM CATALYZED REACTION OF BUTADIENE WITH ALCOHOLS USING ALKYL- AND ARYLSULFINATES AS COCATALYSTS

Autor:	Ryoshu Suzuki, Zen-ichi Yoshida, Masahiro Kagotani, Yoshinao Tamaru
Rok vydání:	1978
Předmět:	chemistry.chemical_classification Chemistry Yield (chemistry) Sodium chemistry.chemical_element Organic chemistry General Chemistry Alkyl Catalysis Palladium
Zdroj:	Chemistry Letters. 7:1329-1332
ISSN:	1348-0715 0366-7022
DOI:	10.1246/cl.1978.1329
Popis:	Sodium alkyl- and arylsulfinates serve as excellent cocatalysts for the palladium catalyzed dimerization of butadiene in alcohols to give 2,7-octadienyl alkyl (Me, Et, Pr, and i-Pr) ethers selectively together with small amounts of 2,7-octadienyl sulfones. 1,3,7-Octatriene is formed in less than 4% yield.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0566157841eaf5d3db3b3528dff126e0 https://doi.org/10.1246/cl.1978.1329 Zobrazit plný text záznamu