Studies of solute - solvent interaction of ethyl acetate with 1-Butyl-3-methylimidazolium tetrafluoroborate at T = (298.15–323.15) K
| Autor: | P.V.V.S. Rama Rao, D. Bala Karuna Kumar, T. Srinivasa Krishna, K. Narendra, Dittakavi Ramachandran |
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| Rok vydání: | 2021 |
| Předmět: |
Materials science
Atmospheric pressure Isentropic process Ethyl acetate Analytical chemistry Condensed Matter Physics Atomic and Molecular Physics and Optics Thermal expansion Electronic Optical and Magnetic Materials Dilution Solvent chemistry.chemical_compound chemistry Ionic liquid Materials Chemistry Isobaric process Physical and Theoretical Chemistry Spectroscopy |
| Zdroj: | Journal of Molecular Liquids. 339:117187 |
| ISSN: | 0167-7322 |
| DOI: | 10.1016/j.molliq.2021.117187 |
| Popis: | In this work, densities and speeds of sound of binary mixtures of 1- butyl −3-methylimidazolium Tetrafluroborate ionic liquid (IL) with Ethyl acetate (EtOAc) have been measured at temperatures 298.15 – 323.15 K at atmospheric pressure. With the help of experimental results, a discussion is carried out on the molecular interactions and the effect of temperature on interactions through excess properties such as excess molar volumes, V m E , excess isentropic compressibility, κ s E , excess speeds of sound, u E , excess molar isentropic compressibility, K s , m E , excess isobaric thermal expansion, α p E . The excess properties are adequately fitted with the Redlich-Kister polynomial equation. The excess partial molar volumes, V ¯ m , 1 E and V ¯ m,2 E ; excess partial molar isentropic compressibilities, K ¯ s,m,1 E and K ¯ s,m,2 E ; excess partial molar volumes, V ¯ m , 1 ° E and V ¯ m , 2 ° E ; excess partial molar isentropic compressibilities, K ¯ s , m , 1 ° E and K ¯ s , m , 2 ° E of the components at infinite dilution also been measured. |
| Databáze: | OpenAIRE |
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