Supramolecular architecture, characterization and computational studies of hydrazinium picrate – An organic charge transfer crystal
| Autor: | R. Markkandan, S. Sivaraman, Sp. Meenakshisundaram |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
010302 applied physics
Materials science Band gap Picrate Intermolecular force Supramolecular chemistry Stacking 02 engineering and technology 021001 nanoscience & nanotechnology 01 natural sciences Characterization (materials science) Supramolecular assembly Crystal Crystallography chemistry.chemical_compound chemistry 0103 physical sciences 0210 nano-technology |
| Zdroj: | Materials Today: Proceedings. 15:654-662 |
| ISSN: | 2214-7853 |
| DOI: | 10.1016/j.matpr.2019.04.134 |
| Popis: | Single crystals of 2-furichydrazinium picrate monohydrate (FHM) grown from ethanol at room temperature belong to the space group P21/c as elucidated from X-ray analysis. Supramolecular assembly is constructed by weak C-H…O, N-H…O and π-π stacking interactions. Intermolecular interactions are analysed by Hirshfeld surface. It exhibits optical limiting property and third-order nonlinear optical character as revealed by Z-scan studies. Band gap energy was estimated by Kubelka-Munk algorithm. Molecular interactions were quantified by Hirshfeld surface analysis and supported well the experimental results. |
| Databáze: | OpenAIRE |
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