The chemistry of the Western Australian rutaceae—VI

Autor:	G.K. Worth, Phillip R. Jefferies
Rok vydání:	1973
Předmět:	chemistry.chemical_classification Thioketal Ketone biology Stereochemistry Hydroxy derivative Organic Chemistry Ether biology.organism_classification Biochemistry chemistry.chemical_compound Alicyclic compound Rutaceae chemistry Drug Discovery Organic chemistry Eriostemon Cis–trans isomerism
Zdroj:	Tetrahedron. 29:903-908
ISSN:	0040-4020
Popis:	Eriobrucinol (1) has been related to hydroxyeriobrucinol (4) by oxidation of the methyl ether of the latter to a ketone (8) and desulphurisation of the derived thioketal. The structures of the coumarins are derived from chemical and spectroscopic arguments. Assignment of the all cis configuration for the alicyclic system is supported by evidence for conformational inversion in the 1′ hydroxy derivative (11).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::05509ca1491e1aa576fe72aac2a23df0 https://doi.org/10.1016/0040-4020(73)80036-5 Zobrazit plný text záznamu