Supercritical water promoted aromatics production using ZSM-5 catalyst

Autor:	Michael T. Timko, Jesse Q. Bond, Siwen Wang, Geoffrey A. Tompsett, Azadeh Zaker
Rok vydání:	2022
Předmět:	Dodecane General Chemical Engineering Organic Chemistry Xylene Aromatization Energy Engineering and Power Technology BTEX Coke Toluene Supercritical fluid chemistry.chemical_compound Fuel Technology chemistry Benzene Nuclear chemistry
Zdroj:	Fuel. 310:122360
ISSN:	0016-2361
DOI:	10.1016/j.fuel.2021.122360
Popis:	Supercritical water assisted aromatization (SCWA) using ZSM-5 was examined for conversion of dodecane and an atmospheric distillate into benzene, toluene, ethyl benzene, and xylene (BTEX) products. When compared with observations made in the absence of water, addition of 15 wt% or less water resulted in several benefits, including enhanced dodecane conversion rate, decreased formation of coke and coke precursors, and increased BTEX yields, retention of crystallinity (>90%), and retention of Bronsted acid site (BAS) density (60%). In contrast, addition of ≥ 25 wt% water resulted in reduced dodecane cracking rate, reduced aromatic production, decreased crystallinity (
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::051824b2076b27cbd668220fc86fe719 https://doi.org/10.1016/j.fuel.2021.122360 Zobrazit plný text záznamu Full Text from ScienceDirect