The Onsager Reciprocity Relations Revisited

Autor: John Ågren
Rok vydání: 2022
Předmět:
Zdroj: Journal of Phase Equilibria and Diffusion. 43:640-647
ISSN: 1863-7345
1547-7037
Popis: The Onsager relations are discussed and it is suggested that they should be interpreted as there is a frame of reference where all the transport processes are independent. The concepts are illustrated with isobarothermal diffusion in simple metallic phases as well as complex ionic systems. A transformation from lattice-fixed frame of reference to number-fixed frame gives the Kirkendall effect as a cross effect.
Databáze: OpenAIRE
Nepřihlášeným uživatelům se plný text nezobrazuje