Leaching of Methyl Isothiocyanate in Plainfield Sand Chemigated with Metam-Sodium

Autor: John M. Harkin, Ibrahim A. M. Saeed, Douglas I. Rouse
Rok vydání: 1996
Předmět:
Zdroj: Pesticide Science. 46:375-380
ISSN: 0031-613X
DOI: 10.1002/(sici)1096-9063(199604)46:4<375::aid-ps370>3.0.co;2-z
Popis: Soil column studies were undertaken to investigate the influence of soil water content and irrigation on leaching, distribution and persistence of methyl isothiocyanate (MITC) in a sandy soil chemigated with the soil fumigant metam-sodium. No leaching was obtained from columns at low water content (0.042 or 0.074 cm 3 cm -3 ). However, 8.4 (±2.8), 34.2 (±7.4) and 119.4 (±8.3) μg of MITC leached from columns at 0.105, 0.137 and 0.168 cm 3 cm -3 water content, respectively. Increased leaching resulted from sprinkler application of 25-mm of water to columns at 0.137 cm 3 cm -3 water content. Leaching of MITC constituted only a small fraction of the amount applied even in the worst case. Methyl isothiocyanate persisted in soil for 15 days at 2°C in varying amounts under the different water regimes. Relatively high amounts of MITC residues (8-12 mg kg -1 soil) were detected in the top 25-cm layer of all the soil columns. Degradation was the major pathway of dissipation for the chemical despite the soil water regime.
Databáze: OpenAIRE