Orthoamide, LX [1]. N,N,N’,N’-Tetraformylhydrazin – ein breit anwendbares Formylierungsmittel für aromatische Verbindungen / Orthoamide, LX [1]. N,N,N’,N’-Tetraformylhydrazine – a Formylation Agent for Aromatic Compounds of Wide Scope

Autor:	Jochen Mezger, Oliver Scherr, Edmont V. Stoyanov, Georg Ziegler, Erwin Haug, Willi Kantlehner
Rok vydání:	2004
Předmět:	Scope (project management) Chemistry Stereochemistry General Chemistry Electrophilic aromatic substitution Formylation
Zdroj:	Zeitschrift für Naturforschung B. 59:357-365
ISSN:	1865-7117 0932-0776
DOI:	10.1515/znb-2004-0402
Popis:	Keywords The reagent system formed from N,N,N’,N’-tetraformylhydrazine (3) and aluminum chloride allows the formylation of aromatic compounds. The scope of the method is comparable with the Olah formylation and the Groß-Rieche procedure, since benzene and fluorobenzene can be formylated. Two formyl groups are transferred from 3 to the aromatic nuclei when a molar ratio 4:1:4 (aluminum chloride/3/aromatic compound) is chosen.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::04dec2aa5a236c51a5163c7f2be3ad3c https://doi.org/10.1515/znb-2004-0402 Zobrazit plný text záznamu