Soot and Tar Production in a Jet-Stirred/Plug-Flow Reactor System: High and Low C2H2Concentration Environments
| Autor: | Laura M. Giovane, John P. Longwell, Arthur L. Lafleur, Joseph A. Marr, Jack B. Howard |
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| Rok vydání: | 1994 |
| Předmět: |
Plug flow
Chemistry General Chemical Engineering Analytical chemistry General Physics and Astronomy Energy Engineering and Power Technology Tar Continuous stirred-tank reactor General Chemistry medicine.disease_cause Combustion Soot chemistry.chemical_compound Fuel Technology medicine Organic chemistry Pyrene Plug flow reactor model Naphthalene |
| Zdroj: | Combustion Science and Technology. 101:301-309 |
| ISSN: | 1563-521X 0010-2202 |
| DOI: | 10.1080/00102209408951878 |
| Popis: | We demonstrate that carbon molecular weight growth chemistry can continue to occur when polycyclic aromatic hydrocarbons (PAH), produced by localized fuel rich pockets within an incinerator, disperse into the near-stoichiometric bulk flow characteristic of the unit. Naphthalene, a model PAH, was added to a near-stoichiometric (φ = 1.2) post-flame combustion flow produced by premixed C2H4/O2/N2/Air combustion in a jet-stirred/plug-flow reactor system (JSR/PFR), and the results compared against those from a fuel rich (φ = 2.2) post-flame combustion flow without naphthalene addition. In both experiments, the PFR was sampled for soot (CH2Cl2 insolubles), tar (CH2Cl2 solubles; PAH), C2H2 and other light gases. The results indicate that naphthalene addition to the φ = 1.2 flow produces PAH in the naphthalene (M W = 128) to cyclopenta[cd]pyrene(MW = 226) fraction at exactly the same total mass concentration as observed in the φ = 2.2 flow without naphthalene addition. Similarly, the rate of growth of so... |
| Databáze: | OpenAIRE |
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