Carbonylative cross-coupling of aryl halides with sodium tetraphenylborate catalyzed by MCM-41-supported bidentate phosphine palladium(II) complex

Autor:	Mingzhong Cai, Shou-Ri Sheng, Guomin Zheng, Hong Zhao
Rok vydání:	2009
Předmět:	chemistry.chemical_classification Process Chemistry and Technology Aryl Aryl halide Inorganic chemistry Halide chemistry.chemical_element General Chemistry Catalysis chemistry.chemical_compound chemistry Polymer chemistry Sodium tetraphenylborate Phosphine Carbon monoxide Palladium
Zdroj:	Catalysis Communications. 11:158-161
ISSN:	1566-7367
DOI:	10.1016/j.catcom.2009.09.016
Popis:	The first heterogeneous carbonylative cross-coupling reaction of aryl halides with sodium tetraphenylborate under an atmospheric pressure of carbon monoxide was achieved in DMF at 80 °C or 130 °C in the presence of a catalytic amount of MCM-41-supported bidentate phosphine palladium(II) complex [MCM-41-2P-Pd(II)] to yield unsymmetrical biaryl ketones in good to high yields. This polymeric palladium catalyst can be reused many times without any decrease in activity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::04ba29fef73ef31c0aa78a8e500e0155 https://doi.org/10.1016/j.catcom.2009.09.016 Zobrazit plný text záznamu Full Text from ScienceDirect