Synthesis of Nitrile-Functionalized Polydentate N-Heterocycles as Building Blocks for Covalent Triazine Frameworks

Autor:	Pascal Van Der Voort, Flore Vanden Bussche, Jonas Everaert, Veronique Van Speybroeck, Thomas S. A. Heugebaert, Christian V. Stevens, Kristof Van Hecke, Maarten Debruyne
Rok vydání:	2021
Předmět:	chemistry.chemical_compound Bipyridine Denticity chemistry Nitrile Ligand Covalent bond Organic Chemistry Rational design Combinatorial chemistry Catalysis 2 2'-Bipyridine Triazine
Zdroj:	Synthesis. 55:333-340
ISSN:	1437-210X 0039-7881
DOI:	10.1055/a-1626-5749
Popis:	Covalent triazine frameworks (CTFs) based on polydentate ligands are highly promising supports to anchor catalytic metal complexes. The modular nature of CTFs allows to tailor the composition, structure, and function to its specific application. Access to a broad range of chelating building blocks is therefore essential. In this respect, we extended the current available set of CTF building blocks with new nitrile-functionalized N-heterocyclic ligands. This paper presents the synthesis of the six ligands which vary in the extent of the aromatic system and the denticity. The new building blocks may help in a rational design of enhanced support materials in catalysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::048f959fe17e21258e49730ab352aa6e https://doi.org/10.1055/a-1626-5749 Zobrazit plný text záznamu