Synthesis of fused azacycle via Overman rearrangement and ring-rearrangement metathesis as key steps

Autor: Sambasivarao Kotha, Ongolu Ravikumar
Rok vydání: 2016
Předmět:
Zdroj: Tetrahedron Letters. 57:1994-1996
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2016.03.087
Popis: A simple and concise approach to fused tricyclic compound containing five stereogenic centers and one nitrogen atom is described starting with a readily available building block dicyclopentadiene. This route involves the Overman rearrangement and ruthenium catalyzed ring-rearrangement metathesis as key steps.
Databáze: OpenAIRE