Esterification of Amine-Carboxyboranes with Orthoformates: A High Yield Synthesis

Autor:	Karen W. Morse, M. Mittakanti, D. A. Feakes
Rok vydání:	1992
Předmět:	chemistry.chemical_compound Chemistry Methylamine Yield (chemistry) Organic Chemistry Pyridine Trimethylamine Amine gas treating Nuclear magnetic resonance spectroscopy Orthoester Medicinal chemistry Catalysis
Zdroj:	Synthesis. 1992:380-382
ISSN:	1437-210X 0039-7881
DOI:	10.1055/s-1992-26117
Popis:	Amine-alkoxycarbonylboranes, amine BH 2 CO 2 R (amine=trimethylamine, methylamine, N-methylmorpholine, pyridine, and diisopropyl (methylamino)methylphosphonate; R=methyl, ethyl, propyl, allyl, and 2-methylpropyl) were prepared in high yield by reacting the amine-carboxyborane with a trialkyl orthoformate in the presence of diethyl ether-boron trifluorate complex as a catalyst
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0469b887c3bcf7604a5cb5a88f9e14b2 https://doi.org/10.1055/s-1992-26117 Zobrazit plný text záznamu