Combining N-heterocyclic carbenes and phosphines: improved palladium(II) catalysts for aryl coupling reactions
| Autor: | Thomas Weskamp, Volker P. W. Böhm, Wolfgang A. Herrmann |
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| Rok vydání: | 1999 |
| Předmět: |
Aryl
Transition metal carbene complex Organic Chemistry chemistry.chemical_element Biochemistry Coupling reaction Stille reaction Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Organic chemistry Physical and Theoretical Chemistry Carbene Phosphine Palladium |
| Zdroj: | Journal of Organometallic Chemistry. 585:348-352 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(99)00237-5 |
| Popis: | Complexes of the type (NHC)Pd(PR3)I2 with bulky N-heterocyclic carbenes (NHC) are efficient catalysts for aryl coupling reactions such as the Suzuki and Stille cross-coupling reaction. These catalysts combine the advantageous stability of bis(carbene) complexes and the good activity of the bis(phosphine) complexes in these reactions. Both arylbromides and arylchlorides can be used as substrates. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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